Compared to semi quantitative peroxides, it has a wider range of applications and better utilization efficiency. Next, I will tell you how to test the universality of Organic peroxides.
We can add sulfide to the organic solvent, so that the peroxide in the organic solvent will oxidize the sulfide air to sulfoxide, and then we can determine the composition of Organic peroxides according to the LC test. Moreover, tetravalent vanadium must first be oxidized by peroxide air before it can become a metal catalyst, so that it can obtain a pentavalent vanadium metal catalyst.
The utilization rate of TBHP in different organic solvents is very good, and the utilization rate of different peroxides in different organic solvents is also very good, with only tert butyl ether peroxide not reflected. The application of BHT can reasonably suppress the formation of peroxides. In a six week experiment, whether stored in N2, gas or glass, or dark brown glass bottles, the increase rate of peroxide composition is less than<10ppm. Whether it is a dark brown bottle or a fully transparent glass bottle, the peroxide content of THF and MeTHF increases after exposure to air.