Tert-Butyl Peroxyneodecanoate

Tert-Butyl Peroxyneodecanoate

Tert-Butyl Peroxyneodecanoate is a peroxyester organic peroxide used as a free-radical initiator for selected polymerization processes. CAS 26748-41-4 and molecular weight 244.4 g/mol identify the active peroxide. Its decomposition profile is suited to polymerization systems where initiator activity must match reaction temperature and residence time.

Product Introduction

Tert-Butyl Peroxyneodecanoate is a peroxyester organic peroxide used as a free-radical initiator for selected polymerization processes. CAS 26748-41-4 and molecular weight 244.4 g/mol identify the active peroxide. Its decomposition profile is suited to polymerization systems where initiator activity must match reaction temperature and residence time.

 

Key Technical Value

 


Low-Temperature Initiation
The peroxide decomposes within a temperature range suitable for selected low-temperature polymerization processes.


Controlled Decomposition
Half-life data at defined temperatures provide a practical reference for matching initiator activity with polymerization conditions.

 

Technical Parameters

 

 

Parameter

Reference Value

Molecular Weight

244.4 g/mol

CAS Number

26748-41-4

Molecular Formula

C14H28O3

Appearance

Clear liquid

Peroxide Assay

≥95%

Active Oxygen

≥6.22%

Density at 0°C

0.91 g/cm³

10 h Half-Life

46°C

1 h Half-Life

64°C

1 min Half-Life

101°C

Maximum Storage Temperature

-10°C

 

Polymerization Applications

 


Ethylene
Used as a free-radical initiator in selected ethylene polymerization and copolymerization processes.


Vinyl Chloride
Applicable to selected vinyl chloride polymerization systems where the decomposition profile matches the reaction temperature.


Vinylidene Chloride
Used in polymerization systems requiring controlled peroxide initiation at relatively low temperatures.


Acrylates & Methacrylates
Applicable to selected acrylate and methacrylate polymerization processes, subject to formulation and process conditions.

 

Initiator Selection

 


Reaction Temperature
Compare the operating temperature with the 46°C, 64°C and 101°C half-life reference points before establishing the working dosage.


Residence Time
Initiator decomposition should correspond with reactor residence time to achieve the required radical generation during polymerization.


Dosage Level
The working concentration depends on monomer type, polymerization temperature, reactor conditions and target conversion.

 

Handling & Storage

 


Cold Storage
The 95% liquid reference grade has a maximum storage temperature of -10°C. Temperature control should be maintained throughout storage.


Container Control
Keep containers closed and use packaging compatible with the selected peroxide formulation and applicable transport requirements.


Documentation
Storage, handling and transportation conditions should follow the current SDS and technical specification for the supplied grade.

 

Quality Control

 


Peroxide Assay
Assay verifies the concentration of active peroxide and provides a primary release parameter for the selected grade.


Active Oxygen
Active oxygen indicates the available peroxide oxygen and supports quantitative batch control.


Appearance & Density
Clear liquid appearance and density at 0°C provide additional physical reference points for incoming and batch quality checks.

 

Supply Specification

 


Concentration
The peroxide concentration should correspond to the required dosing rate and polymerization process.


Liquid Form
The 95% reference grade is a clear liquid with a density of 0.91 g/cm³ at 0°C.


Technical Documents
Product specification, SDS and applicable quality documentation should correspond to the exact concentration and formulation supplied.

 

Application Matching

 


Monomer Compatibility
Confirm the initiator against the monomer, polymerization method and reaction medium before process qualification.


Thermal Profile
The half-life curve provides the basis for assessing decomposition rate at the intended polymerization temperature.


Process Conditions
Temperature, residence time, initiator concentration and target conversion should be evaluated together when establishing the process dosage.

 

Procurement Information

 


Specification
Provide the required peroxide concentration, polymer system, reaction temperature and expected quantity for technical specification review.


Qualification
Confirm assay, active oxygen, half-life data, storage temperature and documentation before production use.


Delivery
Confirm packaging, temperature-controlled storage and applicable transport conditions according to the selected grade.

 

FAQ

 

 

Q: What is the CAS number of Tert-Butyl Peroxyneodecanoate?

A: The CAS number is 26748-41-4.

Q: What is the molecular weight?

A: The molecular weight is 244.4 g/mol, with molecular formula C14H28O3.

Q: What are the half-life temperatures?

A: For the reference 95% liquid grade, the half-life temperatures are 46°C at 10 hours, 64°C at 1 hour and 101°C at 1 minute.

Q: Which polymerization systems use this initiator?

A: Applications include selected ethylene, vinyl chloride, vinylidene chloride, acrylate and methacrylate polymerization and copolymerization processes.

Q: What information is required for product selection?

A: The main inputs are peroxide concentration, monomer type, polymerization temperature, residence time, target conversion and required technical documentation.

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